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isophorone diisocyanate : ウィキペディア英語版
isophorone diisocyanate

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Isophorone diisocyanate (IPDI) is an organic compound in the class known as isocyanates. More specifically, it is an aliphatic diisocyanate. It is produced in relatively small quantities, accounting for (with hexamethylene diisocyanate) only 3.4% of the global diisocyanate market in the year 2000.〔
〕 Aliphatic diisocyanates are used, not in the production of polyurethane foam, but in special applications, such as enamel coatings which are resistant to abrasion and degradation from ultraviolet light. These properties are particularly desirable in, for instance, the exterior paint applied to aircraft.
==Synthesis==
There are five steps to the synthesis of pure IPDI:〔
* ''Condensation:'' Conversion of acetone with a catalyst to produce isophorone
* ''Hydrocyanation:'' Reaction of the isophorone with hydrogen cyanide to form isophorone nitrile
* ''Reductive amination:'' Reaction of the isophorone nitrile with ammonia, hydrogen and a catalyst, to form a mixture of isophorone diamine conformers (25/75 cis/trans)
* ''Phosgenation:'' Reaction of the isophorone diamine with phosgene to form a crude mixture containing IPDI conformers (25/75 cis/trans)
* ''Purification:'' Distillation of the crude IPDI to extract pure IPDI

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「isophorone diisocyanate」の詳細全文を読む



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